Nanowires Fabbed on Silicon
CAMBRIDGE, Mass., May 9, 2008 -- Nanowire devices have been fabricated by integrating silicon integrated circuits (ICs) manufacturing technology with photolithography. The new technique could lead to the development of a new class of ICs that combine light emitters with silicon technology.
Applied scientists at Harvard University, in collaboration with researchers from the German universities of Jena, Göttingen, and Bremen, developed the high-volume, low-cost fabrication method for integrating nanowire photonic devices directly onto silicon.
While semiconductor nanowires -- rods with an approximate diameter of one-thousandth the width of a human hair -- can be easily synthesized in large quantities using inexpensive chemical methods, reliable and controlled strategies for assembling them into functional circuits have posed a major challenge. By incorporating spin-on glass technology used in silicon integrated circuits manufacturing and photolithography (transferring a circuit pattern onto a substrate with light), the team demonstrated a new method that may one day be suitable for high-volume commercial production.
Federico Capasso and Mariano Zimmler of the Harvard School of Engineering and Applied Sciences. (Photo courtesy Eliza Grinnell, Harvard School of Engineering and Applied Sciences)
The project was spearheaded by graduate student Mariano Zimmler and Federico Capasso, the Robert L. Wallace Professor of Applied Physics and Vinton Hayes Senior Research Fellow in Electrical Engineering, both of Harvard's School of Engineering and Applied Sciences (SEAS); and professor Carsten Ronning of the University of Jena. Their findings will be published in Nano Letters.
"Because our fabrication technique is independent of the geometrical arrangement of the nanowires on the substrate, we envision further combining the process with one of the several methods already developed for the controlled placement and alignment of nanowires over large areas," said Capasso. "We believe the marriage of these processes will soon provide the necessary control to enable integrated nanowire photonic circuits in a standard manufacturing setting."
The structure of the team's nanowire devices is based on a sandwich geometry: a nanowire is placed between the highly conductive substrate, which functions as a common bottom contact, and a top metallic contact, using spin-on glass as a spacer layer to prevent the metal contact from shorting to the substrate. As a result current can be uniformly injected along the length of the nanowires. These devices can then function as LEDs, with the color of light determined by the type of semiconductor nanowire used.
To demonstrate the potential scalability of their technique, the team fabricated hundreds of nanoscale ultraviolet LEDs by using zinc oxide nanowires on a silicon wafer. More broadly, because nanowires can be made of materials commonly used in electronics and photonics, they hold great promise for integrating efficient light emitters, from ultraviolet to infrared, with silicon technology. The team plans to further refine their novel method with an aim towards electrically contacting nanowires over entire wafers.
The basic structure of the nanowire devices is based on a sandwich geometry in which a nanowire (n-type zinc oxide) is placed between the substrate (heavily doped p-type silicon) and a top metallic contact, using spin-on glass as an insulating spacer layer to prevent the metal contact from shorting to the substrate [as shown in (a) and (b)]. This allows for uniform injection of current along the length of the nanowire. A finished wafer using the team's method is shown in (c), with a typical device shown in (d). Note that a stray nanowire intercepts the device on the upper part of (d). The oval feature surrounding the stray nanowire is due to the varying thickness of the spin-on glass film. When a voltage is applied to this device, it emits ultraviolet light (as shown in image (e) obtained with a CCD camera) with a peak wavelength of approx. 380 nm. (Image courtesy of the lab of Federico Capasso, Harvard School of Engineering and Applied Sciences)
"Such an advance could lead to the development of a completely new class of integrated circuits, such as large arrays of ultrasmall nanoscale lasers that could be designed as high-density optical interconnects or be used for on-chip chemical sensing," said Ronning. The researchers have filed for US patents covering their invention.
The team's co-authors are postdoctoral fellow Wei Yi and Venkatesh Narayanamurti, the John A. and Elizabeth S. Armstrong Professor and dean, both of Harvard's School of Engineering and Applied Sciences; graduate student Daniel Stichtenoth, University of Göttingen; and postdoctoral fellow Tobias Voss, University of Bremen.
The research was supported by the National Science Foundation, the German Research Foundation and two Harvard-based centers, the National Science Foundation Nanoscale Science and Engineering Center and the Center for Nanoscale Systems, a member of the National Nanotechnology Infrastructure Network.
For more information, visit: www.seas.harvard.edu
- The technology of generating and harnessing light and other forms of radiant energy whose quantum unit is the photon. The science includes light emission, transmission, deflection, amplification and detection by optical components and instruments, lasers and other light sources, fiber optics, electro-optical instrumentation, related hardware and electronics, and sophisticated systems. The range of applications of photonics extends from energy generation to detection to communications and...
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