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Hybrid ‘Wonder Material’ Creates Efficient LEDs

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CAMBRIDGE, England, OXFORD, England, and MUNICH, Aug. 7, 2014 — A new type of perovskite — touted as a “wonder material” — has been used to create a new type of LED that has the potential to create more efficient light sources than those that rely on conventional solar cells.

A team from the University of Cambridge, the University of Oxford and the Ludwig Maximilian University of Munich has developed a new type of perovskite called organometal halide perovskite containing a mixture of lead, carbon-based ions and halogen ions.

“These organometal halide perovskites are remarkable semiconductors,” said lead researcher Zhi-Kuang Tan, a PhD candidate at the University of Cambridge's Cavendish Laboratory.


Perovskite-based LEDs. Courtesy of Zhi-Kuang Tan/University of Cambridge.

“We have designed the diode structure to confine electrical charges into a very thin layer of the perovskite, which sets up conditions for the electron hole capture process to produce light emission,” he said. 

The new LEDs were made using a simple, scalable process in which a perovskite solution was spin-coated onto a substrate. The process should be inexpensive to manufacture on a large scale, according to the researchers, as it does not require additional steps.

The new hybrid material can be tuned to emit light in a variety of colors as well, making it useful in the development of flexible color displays, lighting and optical communication applications.

“This technology could provide a lot of value to the ever growing flat-panel display industry,” Tan said.

Now, the researchers are working to increase the new LEDs’ efficiency and potentially use them for diode lasers. The first commercially produced perovskite-based LEDs could be available within the next five years, they said.

The research was published in Nature Nanotechnology. (doi: 10.1038/nnano.2014.149).

For more information, visit www.cam.ac.uk.
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Published: August 2014
Glossary
perovskite
The term perovskite refers to a specific crystal structure commonly found in various materials. Perovskite structures have a cubic arrangement of oxygen ions, forming a framework within which other cations (positively charged ions) are located. This crystal structure was named after the mineral perovskite, which has the chemical formula CaTiO3 and was first discovered in the Ural Mountains of Russia. The general formula for the perovskite structure is ABX3, where: A represents a larger...
Cavendish LaboratoryenergyEnglandEuropeGermanyhalidesLight SourcesLudwig Maximilian University of MunichmanufacturingMaterialsperovskiteResearch & Technologysolar cellsUniversity of CambridgeUniversity of Oxfordorganometal halide perovskitesZhi-Kuang TanLEDs

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