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Lithographic Technology Aids in Ultrathin Optical Fabrication

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Researchers from MIT have developed a low-cost optical fabrication method that enables the production high-quality thin mirrors and silicon wafers. The method developed by the team, led by research scientist and lead author Youwei Yao, reshapes thin-plate materials in a way that eliminates distortion and enables researchers to bend surfaces more arbitrarily into the precise and complex shapes needed for high-level complex systems.

Technologies that depend on lightweight, high-precision optical systems, such as space telescopes, x-ray mirrors, and display panels, have developed significantly over the past several decades, but more progress has been limited by seemingly simple challenges. For example, the surfaces of mirrors and plates with microstructures that are necessary in these optical systems can be distorted by stressed surface coating materials, degrading optics quality. This is especially true for ultralightweight optical systems, such as space optics, where traditional optical fabrication methods struggle to meet exacting shape requirements.

Yao and his team envision that their thinner and more easily deformable surfaces could find use in broader applications such as augmented reality headsets and larger telescopes that can be sent into space at lower cost.
Silicon mirrors with stress correction patterns etched into a thermal oxide layer. Courtesy of Youwei Yao, MIT.
Silicon mirrors with stress correction patterns etched into a thermal oxide layer. Courtesy of Youwei Yao/MIT.
“Using stress to deform optical or semiconductor surfaces is not new, but by applying modern lithographic technology, we can overcome many of the challenges of existing methods,” Yao said.

The team’s work builds on the research of Brandon Chalifoux, who is now an assistant professor at the University of Arizona. Chalifoux worked with the team on earlier papers to develop a mathematical formalism to connect surface stress states with deformations of thin plates, as part of his doctorate in mechanical engineering.

In this new approach, Yao developed a novel arrangement of stress patterns for precisely controlling general stress. Substrates for optical surfaces are first coated on the backside with thin layers of high-stress film, made of materials such as silicon dioxide. Novel stress patterns are lithographically printed into the film so that researchers can change the properties of the material in specific areas. Selectively treating the film coating in different areas controls where stress and tension is applied across the surface. And because the optical surface and the coating are adhered together, manipulating the coating material also reshapes the optical surface accordingly.

“You’re not adding stress to make a shape, you’re selectively removing stress in specific directions with carefully designed geometric structures, like dots or lines,” said Mark Schattenburg, senior research scientist and director of the Space Nanotechnology Laboratory (SNL). “That’s just a certain way to give a target stress relief at a single place in the mirror that can then bend the material.”

Since 2017, the SNL team has worked with NASA Goddard Space Flight Center (GSFC) to develop a process to correct the shape distortion of x-ray telescope mirrors caused by coating stress. The research originated from a project of building x-ray mirrors for NASA’s Lynx next-generation x-ray telescope mission concept, which requires tens of thousands of high-precision mirrors. Due to the task of focusing x-rays, the mirrors must be very thin to gather x-rays efficiently. However, mirrors lose stiffness rapidly as they are thinned, becoming easily distorted by the stress from their reflective coatings — a nanometers-thick iridium layer coated on the front side for the purpose of reflecting x-rays.

“My team at GSFC has been making and coating thin x-ray mirrors since 2001,” said William Zhang, x-ray optics group leader at GSFC. “As the quality of x-ray mirrors has improved continually in the last several decades following technological advancements, distortion caused by coatings has become an increasingly serious problem.”

Yao and his team developed a lithographic stress patterning method, successfully combining several different techniques, to achieve excellent removal of distortion when applied to x-ray mirrors made by the group.

After this initial success, the team decided to extend the process to more general applications, such as freeform shaping of mirrors and thin substrates, but they met a major obstacle.

“Unfortunately, the process developed for GSFC can only precisely control a single type of surface stress, the so-called equibiaxial, or rotationally uniform, stress,” Chalifoux said. “Equibiaxial stress states can only achieve bowl-like local bending of the surface, which cannot correct potato-chip or saddle-shape distortions. To achieve arbitrary control of surface bending requires control of all three terms in the so-called surface stress tensor.”

To achieve full control of the stress tensor, Yao and his team further developed the technology, eventually inventing what they call stress tensor mesostructures (STMs), which are quasi-periodic cells arrayed on the back surface of thin substrates, composed of gratings superimposed on stressed coatings.

“By rotating the grating’s orientation in each unit cell and changing the area fraction of selected areas, all three components of the stress tensor field can be controlled concurrently with a simple patterning process,” Yao said.

The team spent more than two years developing this concept.

“We encountered a series of difficulties in the process,” Schattenburg said. “Freeform shaping of silicon wafers with nanometer precision requires a synergy of metrology, mechanics, and fabrication. By combining the lab’s decades of experience in surface metrology and microfabrication with graduate-student-developed thin-plate modeling and optimization tools, we were able to demonstrate a general substrate shape control method that is not limited to only bowl-like surface bending.”

The approach enabled the team to imagine new applications beyond the initial task of correcting coating-distorted x-ray mirrors. “When forming thin plates using traditional methods, it is difficult to be precise because most of the methods generate parasitic or residual stresses that lead to secondary distortion and spring-back after processing,” said Jian Cao, a professor of mechanical engineering at Northwestern University, who was not involved with the work. “But the STM stress-bending method is quite stable, which is especially useful for optics-related applications.”

Yao and his colleagues expect to control stress tensors dynamically in the future.

“Piezoelectric actuation of thin mirrors, which is used in adaptive optics technology, has been under development for many years, but most methods can only control one component of the stress,” Yao said. “If we can pattern STMs on thin, piezo-actuated plates, we would be able to extend these techniques beyond optics to interesting applications such as actuation on microelectronics and soft robotics.”

The research was published in Optica (www.doi.org/10.1364/OPTICA.445379).

Photonics Spectra
Jul 2022
GLOSSARY
photolithography
A lithographic technique using an image produced by photography for printing on a print-nonprint, sectioned surface.
wafer
A cross-sectional slice cut from an ingot of either single-crystal, fused, polycrystalline or amorphous material that has refined surfaces either lapped or polished. Wafers are used either as substrates for electronic device manufacturing or as optics. Typically, they are made of silicon, quartz, gallium arsenide or indium phosphide.
thin film
A thin layer of a substance deposited on an insulating base in a vacuum by a microelectronic process. Thin films are most commonly used for antireflection, achromatic beamsplitters, color filters, narrow passband filters, semitransparent mirrors, heat control filters, high reflectivity mirrors, polarizers and reflection filters.
mirror
A smooth, highly polished surface, for reflecting light, that may be plane or curved if wanting to focus and or magnify the image formed by the mirror. The actual reflecting surface is usually a thin coating of silver or aluminum on glass.
adaptive optics
Optical components or assemblies whose performance is monitored and controlled so as to compensate for aberrations, static or dynamic perturbations such as thermal, mechanical and acoustical disturbances, or to adapt to changing conditions, needs or missions. The most familiar example is the "rubber mirror,'' whose surface shape, and thus reflective qualities, can be controlled by electromechanical means. See also active optics; phase conjugation.
Research & Technologyopticsmanufacturingfabricationphotolithographywafersilicon photonicsthin filmMirrorMITadaptive opticsstresspiezoroboticsmicroelectronicsopticaTechnology News

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