Search
Menu
Cognex Corp. - Smart Sensor 3-24 GIF LB

Nanoparticles Intensify QDs’ Glow

Facebook X LinkedIn Email
By linking individual semiconductor quantum dots with gold nanoparticles, scientists at Brookhaven National Laboratory have demonstrated the ability to enhance the intensity of light emitted by individual quantum dots by up to 20 times.

According to the group, the precision method for making the light-emitting particle clusters will greatly advance scientists’ ability to study and modify the optical properties of quantum dots, and it could eventually lead to improved solar energy conversion devices, light-controlled electronics and biosensors.


Oleg Gang, left, and Mircea Cotlet at Brookhaven's Center for Functional Nanomaterials.

“Quantum dots — tiny crystals of semiconductor materials that fluoresce, or emit light, in response to photoexcitation — have enormous potential for use in a wide range of fields from solar energy conversion to computing and medicine,” said Mircea Cotlet, a physical chemist at Brookhaven’s Center for Functional Nanomaterials (CFN) and lead author on the study published online in the journal ChemComm. “But many factors can influence the light they emit, and it’s hard to sort out the contributions of these factors in large samples due to the inherent ensemble averaging. Building single-molecule structures at the CFN seemed the ideal way to tease out these effects.”

The Brookhaven team recently developed a precision technique for building such nanosized structures using short strands of DNA as a highly specific “glue” to link particles together.

“DNA consists of two strands with complementary pairings of bases that stick together in only one way,” explained Oleg Gang, leader of the team that developed the technique. “By varying the length of the individual strands and attaching complementary pieces to the particles we want to join, and anchoring the whole process on an assembly surface, we can precisely control the construction of individual nanoclusters.”

In the current study, the team used this multistep process to attach semiconductive quantum dots to gold nanoparticles. Metallic materials are known to affect the optical properties of quantum dots, either by enhancing or inhibiting photoluminescence, depending on a range of factors, including the size and shape of the materials, the distance between them, and the wavelength of light used to induce photoexcitation.

Meadowlark Optics - Building system MR 7/23

The precision assembly technique allowed the scientists to control the size, shape and distance factors to a high degree of precision and to test the effect of wavelength in isolation. They specifically chose two wavelengths to test: one close to the so-called “plasmon resonance” of the gold nanoparticles — that is, a wavelength that induces a collective oscillation of the material’s conductive electrons, leading to strong absorption of light at that wavelength — and one outside this range.

The wavelength within the plasmon resonance range enhanced photoluminescence approximately fourfold when compared with the luminescence achieved by the wavelength outside the plasmon resonance range. When compared with the photoluminescence of individual quantum dots not linked to gold nanoparticles, the resonant wavelength enhanced photoluminescence of the gold-linked quantum dots by an order of magnitude.


Photoluminescence enhancement is demonstrated at the single-molecule level for two-particle systems composed of a quantum dot (Qdot) and gold nanoparticle (AuNP) linked by double-stranded DNA (dsDNA) when optically excited with wavelengths within the surface plasmon resonance range of the gold nanoparticle.


“This ability to control the excitonic properties in plasmonic fluorescent quantum dots is essential to the development of devices such as solar cells, light- emitting diodes, or optical circuits and might improve the sensitivity of quantum dot based biosensing assays,” Cotlet said.

In addition to Cotlet and Gang from Brookhaven, Mathew Maye (now at Syracuse University) contributed to this work. The research was performed at the Center for Functional Nanomaterials at Brookhaven National Laboratory and was supported by the Office of Science of the US Department of Energy.

The Center for Functional Nanomaterials at BNL is one of the five DoE Nanoscale Science Research Centers, premier national user facilities for interdisciplinary research at the nanoscale that are supported by the DoE Office of Science. Together the NSRCs comprise a suite of complementary facilities that provide researchers with state-of-the-art capabilities to fabricate, process, characterize and model nanoscale materials, and they constitute the largest infrastructure investment of the National Nanotechnology Initiative. The NSRCs are located at DoE’s Argonne, Brookhaven, Lawrence Berkeley, Oak Ridge, and Sandia and Los Alamos national laboratories.

For more information, visit:  www.bnl.gov 



Published: July 2010
Glossary
nano
An SI prefix meaning one billionth (10-9). Nano can also be used to indicate the study of atoms, molecules and other structures and particles on the nanometer scale. Nano-optics (also referred to as nanophotonics), for example, is the study of how light and light-matter interactions behave on the nanometer scale. See nanophotonics.
photoluminescence
The state of optically excited luminescence. Luminescence refers to the light emitted by excited atoms or ions as they decay to lower energy levels.
quantum dots
A quantum dot is a nanoscale semiconductor structure, typically composed of materials like cadmium selenide or indium arsenide, that exhibits unique quantum mechanical properties. These properties arise from the confinement of electrons within the dot, leading to discrete energy levels, or "quantization" of energy, similar to the behavior of individual atoms or molecules. Quantum dots have a size on the order of a few nanometers and can emit or absorb photons (light) with precise wavelengths,...
AmericasBasic ScienceBiophotonicsbiosensorsBrookhaven National Laboratorycrystalsemit lightenergyenergy conversion devicesfluorescegold nanoparticlesgreen photonicsLight Sourceslight-controlled electronicslight-emitting particle clustersMatthew MayeMircea CotletnanonanoclustersnanoparticlesNew YorkOleg Gangoptical propertiesphotoluminescencephtoexcitationqdsquantum dotsResearch & TechnologysemiconductorsSensors & Detectorssolar cellsUS Department of EnergyLEDs

We use cookies to improve user experience and analyze our website traffic as stated in our Privacy Policy. By using this website, you agree to the use of cookies unless you have disabled them.