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Optically Active Quantum Dots Embedded in Nanowires

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Daniel S. Burgess

Investigators at the Swiss Federal Institute of Technology in Zurich have reported the fabrication of quantum dots in nanowires that display a level of brightness an order of magnitude higher than self-assembled InAs dots. They suggest that the work may have an impact on the development of so-called quantum dot molecules for quantum information processing as well as of devices that integrate electronics and optics, particularly because the structures can be grown on silicon.

The researchers produced the structures by low-pressure metallorganic vapor phase epitaxy, embedding 15-nm alloys of GaAsP in 200- to 500-nm-long segments of GaAsP with a higher bandgap within the GaP nanowires. To characterize the optical properties of the embedded quantum dots, they used 3-ps pulses of 430-nm light from a mode-locked Ti:sapphire laser to excite the dots and collected photoluminescence and photon correlation data on the response using a spectrometer, a streak camera and a pair of single-photon-counting avalanche photodiodes. The scientists attributed the high apparent brightness of the dots to the fact that they are not embedded in a high-refractive-index host material.

The ability to define the position of the quantum dots in the nanowire, they suggest, will be useful in the design of chainlike structures in which charges or photons are passed from one quantum dot to another.

Nano Letters, June 16, 2005, online article, doi:10.1021/nl050802y.
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Published: August 2005
Glossary
nano
An SI prefix meaning one billionth (10-9). Nano can also be used to indicate the study of atoms, molecules and other structures and particles on the nanometer scale. Nano-optics (also referred to as nanophotonics), for example, is the study of how light and light-matter interactions behave on the nanometer scale. See nanophotonics.
quantum dots
A quantum dot is a nanoscale semiconductor structure, typically composed of materials like cadmium selenide or indium arsenide, that exhibits unique quantum mechanical properties. These properties arise from the confinement of electrons within the dot, leading to discrete energy levels, or "quantization" of energy, similar to the behavior of individual atoms or molecules. Quantum dots have a size on the order of a few nanometers and can emit or absorb photons (light) with precise wavelengths,...
Featuresmetallorganic vapor phase epitaxynanoquantum dotssiliconspectroscopy

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